Huludao Zinc Plant adopts wet-fire combined process to treat examples of smoke-containing dust

The zinc sulfide concentrate of Huludao Zinc Plant in China adopts high temperature roasting process. The high-temperature dust collected by the high-temperature electric dust collection and the soot collected by the secondary roasting of the rotary kiln and the double-blind ash and electric dust collected by the zinc concentrate of the first, second and fourth smelters of Shuikoushan Mining Bureau are high in cadmium. It is the raw material for cadmium. The components of this cadmium-containing soot are listed in Table 1.

Table 1 Composition of cadmium-containing soot

category

Zn

Cd

Pb

Cu

As

Fe

Ss

Sso 4

High temperature dust

40±

5~6

4~5

-

-

-

-

-

Cadmium dust

18~20

18~23

-

-

-

-

-

-

Double ash

47~52

0.8 to 1.1

6~12

0.4 to 0.7

0.2 to 0.8

11~13

1 to 2

2 to 4

Electric dust

35~40

2 to 4

15~25

0.2 to 0.3

0.3 to 1

0.3 to 1.2

1.2 to 3

2 to 4

The third smelter of Shuikoushan Mining Bureau uses the all-wet process to treat the soot. The basic process is similar to the electrowinning process of Cu-Cd slag. The recovery rate of cadmium smelting is 88.75%, and the grade of cadmium is 99.99%.

The Huludao Zinc Plant uses a wet-fire combined process to treat cadmium-containing soot. The production process is shown in Figure 1. The main advantage of this method is a simple process, high metal recoveries, the total recovery of cadmium in 1980 reached 71.29 percent, higher product quality, purity cadmium refined output stable at 99.995%.

Figure 1 Huludao zinc plant extracts cadmium from soot

The plant successfully tested the crude cadmium refining process in 1958. The cadmium rectification tower has a height of 5.585m and consists of 28 trays with a tray size of 360×250mm. The technical conditions for rectification are as follows:

Enter the furnace crude cadmium grade /% 98 ~ 99

Combustion chamber temperature / K 1343 ~ 1353

Bottom temperature / K 1313 ~ 1323

Upper temperature / K 893 ~ 913

Gas condenser temperature / K 953 ~ 973

Liquid condenser temperature / K 843 ~ 863

Feeder temperature / K 773 ~ 823

Fine cadmium pot temperature / K 753 ~ 773

Crude cadmium melting pot temperature / K 723 ~ 773

Unit heating surface productivity / (kg · (m 2 · d) -1 ) 965 ~ 980

Cadmium recovery rate /% >99.7

Direct production rate of cadmium /% >98

Production of 1t cadmium consumption /%

Caustic soda / kg 12 ~ 14

Coal / kg 650 ~ 700

Water / t 1.5 ~ 2

The cadmium slag component discharged from the bottom of the column is: 70% to 72% Cd, 13% to 15% Pb, 0.02% to 1.08% Zn, 3.1% to 4.6% Cu, 2.1% to 3.1% Fe, 3.5% to 4.9% As , 0.1% to 0.2% T1. This slag is sent to the recovery tank .

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